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The Controversy about Electron Spin

In Holland the State University Leiden was a prominent centre for theoretical physics. At the end of the nineteenth and the beginning of the twentieth century, Hendrik Antoon Lorentz (1853-1929) had worked there. His successor, on the recommendation of Albert Einstein, was the Austrian Paul Ehrenfest, whom Wolfgang Pauli had already met in 1922 during the "Bohr Festival" in Göttingen.

In 1925 Ehrenfest's assistants Georg Eugen Uhlenbeck (1900-1988) and Samuel Abraham Goudsmit (1902-1978) had the idea of electron spin, i.e. a clearly imaginable rotation of the electron on its axis. This hypothesis had already been proposed by Ralph Kronig (1904-1995), who was later Pauli's assistant in Zurich.

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Wolfgang Pauli and Paul Ehrenfest
© CERN, Geneva

Many theoretical physicists, Pauli among them, considered this idea to be inacceptable and too descriptive. On the other hand, at this time Heisenberg's matrix mechanics were being developed, which were anything but pictorial, in which the conception of electron orbits in the atom was expressly avoided. With the aid of electron spin, however, certain properties of the hydrogen spectra were able to be interpreted satisfactorily. The main difficulty was the difference of a factor 2 between the calculated and observed doublet splitting. So a lively oral and written discussion broke out. Characteristically, the problem was considered to have been resolved after Pauli was able to be convinced. In retrospect Goudsmit wrote in 1965 that Pauli had abandoned his critical, negative position in March 1926 and had informed him of this on a postcard. Today, electron spin is considered to be a quantum mechanical property with the dimension of angular momentum. It can take only two values, +1/2 and -1/2, in quantum mechanical units. Electrons are hence governed by the Pauli principle.
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